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Beilstein J. Org. Chem. 2015, 11, 42–49, doi:10.3762/bjoc.11.7
Graphical Abstract
Scheme 1: Structural motif of two important types of catalysts and typical substrate specificity in the copol...
Scheme 2: Binuclear Zn(II) complexes [LZn2](CF3SO3)2 (1, KOP113) and [LZn2](p-TSO3)2 (2, KOP115) explored in ...
Scheme 3: Copolymerisation of CO2 and cyclohexene oxide (*: end groups of the polymer chain).
Figure 1: Time-resolved IR spectra of the copolymerisation of CO2 and CHO with catalyst 1 showing the formati...
Figure 2: Time–concentration profile of the copolymerisation of CO2 and CHO in the presence of catalytic amou...
Figure 3: Carbonate region of the time-resolved IR spectra recorded during the copolymerisation of CO2 and cy...
Figure 4: Time–concentration profile of the copolymerisation of CO2 and CHO in the presence of catalytic amou...
Scheme 4: Proposed inner-sphere mechanism for the copolymerisation of CO2 and CHO with binuclear zinc complex...